Substance
ID:715148
Names and Identifiers
Synonyms
Bismuth(III) nitrate pentahydrate五水合硝酸铋(III)
IUPAC Traditional name
bismuth(3+) ion pentahydrate trinitrate
IUPAC name
bismuth(3+) ion pentahydrate trinitrate
Properties
Product Information
Purity
98%
Physical Property
Density
2.83
Melting Point
30°C dec.
Safety Information
GHS Precautionary statements
P221-P210-P305+P351+P338-P302+P352-P405-P501A
European Hazard Symbols
Irritant (Xi)
Oxidising (O)GHS Pictograms
Oxidizing gases, category 1
Oxidizing liquids, categories 1,2,3
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS Hazard statements
H272-H315-H319-H335
Safety Statements
17-26-37-60
Hazard Class
5.1
Risk Statements
8-36/37/38
UN Number
UN1477
Packing Group
II
TSCA Listed
是
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Useful, easily handled oxidizing and nitrating agent in organic synthesis. Montmorillonite KSF acidic clay impregnated with bismuth nitrate was found to be an excellent reagent for high-yield aromatic nitration: Tetrahedron Lett., 41, 8017 (2000). Phenols can be nitrated with the salt itself in acetone, or without solvent: J. Org. Chem., 70, 9071 (2005). In the presence of montmorillonite, alcohols can be oxidized to carbonyl compounds: Synth. Commun., 31, 2691 (2001). Reagent for deprotection of oximes: Synthesis, 1010 (2001), and hydrazones: Synth. Commun., 32, 1917 (2001). Thioamides and thioureas are readily converted to their oxo-analogs: Tetrahedron Lett., 44, 591 (2003).
• Catalyst for a convenient, high-yield Michael addition of various substrates, including amines, imidazoles and indoles, to enones: J. Org. Chem., 68, 2109 (2003). Efficient catayst for tetrahydropyranylation and depyranylation of alcohols: Eur. J. Org. Chem., 4891 (2005).
• For a brief feature on uses of the reagent in organic synthesis, see: Synlett, 2699 (2005).