Substance
ID:714528
Names and Identifiers
IUPAC Traditional name
M-bromofluorobenzene
IUPAC name
1-bromo-3-fluorobenzene
Synonyms
1-Bromo-3-fluorobenzene1-溴-3-氟苯3-Bromofluorobenzene
Registration numbers
CAS Number
MDL Number
EC Number
Beilstein Number
Properties
Physical Property
Boiling Point
148-150°C
Melting Point
-8°C
Density
1.594
Refractive Index
1.5275
Flash Point
46°C(115°F)
Safety Information
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
European Hazard Symbols
Harmful (X)Risk Statements
10-22-36/38
TSCA Listed
是
GHS Precautionary statements
P280H-P305+P351+P338
Safety Statements
26-36/37
RTECS
DA1225000
Hazard Class
3
UN Number
UN1993
Packing Group
III
GHS Hazard statements
H226-H302-H315-H319
Product Information
Purity
99%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Lithiation with Li 2,2,6,6-tetramethylpiperidide (LTMP) at -75o occurs at the 2-position. The yield of 2-bromo-6-fluorobenzoic acid obtained after carboxylation can be increased to 93% by the use of a base consisting of a 9:1 mixture of LTMP and LDA: Tetrahedron Lett., 37, 6551 (1996).