Substance

ID:714268

Names and Identifiers
IUPAC Traditional name
lutidine
IUPAC name
2,6-dimethylpyridine
Synonyms
2,6-Dimethylpyridine2,6-Lutidine2,6-二甲基吡啶
Registration numbers
MDL Number
CAS Number
Beilstein Number
EC Number
Merck Index
Properties
Safety Information
Hazard Class
3
UN Number
UN1993
Packing Group
III
European Hazard Symbols
Harmful Harmful (X)
GHS Hazard statements
H226-H302-H315-H319-H335
GHS Pictograms
GHS02
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS Precautionary statements
P280H-P305+P351+P338
Risk Statements
10-22-36/37/38
RTECS
OK9700000
Storage Warning
Hygroscopic
TSCA Listed
Safety Statements
23-26-36/37-60
Physical Property
Refractive Index
1.4970
Density
0.923
Flash Point
33°C(91°F)
Melting Point
-7°C
Boiling Point
143-145°C
Product Information
Purity
98+%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• This hindered base has been recommended for the exhaustive methylation of aromatic amines: J. Org. Chem., 35, 1558 (1970), and for the Rosenmund reduction of acyl halides to aldehydes: Synthesis, 767 (1976).
• Base catalyst for the silylation of highly-hindered secondary or tertiary alcohols by tert-Butyldimethylsilyl trifluoromethanesulfonate, A12174.
• For monometallation with potassium amide in liquid ammonia, and subsequent carboethoxylation with diethyl carbonate, see: Org. Synth. Coll., 6, 611 (1988).