Substance
ID:714036
Names and Identifiers
IUPAC Traditional name
phenylmethanesulfonyl chloride
IUPAC name
phenylmethanesulfonyl chloride
Synonyms
α-甲苯磺酰氯alpha-Toluenesulfonyl chloridePhenylmethanesulfonyl chlorideBenzylsulfonyl chloride
Registration numbers
CAS Number
Beilstein Number
EC Number
MDL Number
Properties
Safety Information
European Hazard Symbols
Corrosive (C)Safety Statements
26-36/37/39-45
GHS Hazard statements
H314-H318
Hazard Class
8
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Storage Warning
Moisture Sensitive
UN Number
UN3096
Risk Statements
34
TSCA Listed
是
GHS Precautionary statements
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
Packing Group
II
Physical Property
Melting Point
89-94°C
Boiling Point
120°C/10mm
Product Information
Purity
99%
Molecule Details
No Data Available
Click here to submit data
Molecular Spectra
No Data Available
Click here to submit data
References
• Reagent for protection of amino groups as benzylsulfonamides which can be cleaved reductively, e.g. Na/NH3, Raney Ni/H2: J. Am. Chem. Soc., 79, 639, 645 (1957), or by photolysis: Tetrahedron Lett., 1029 (1979).
• Alcohols can also be protected, e.g. in the presence of 2,6-lutidine, as benzylsulfonates which can be cleaved with NaNH2 in DMF: Bull. Chem. Soc. Jpn., 59, 1587 (1986).