Substance

ID:713495

Names and Identifiers
IUPAC Traditional name
acetone
IUPAC name
propan-2-one
Synonyms
Acetone丙酮
Registration numbers
CAS Number
EC Number
Beilstein Number
MDL Number
Merck Index
Properties
Physical Property
Boiling Point
56°C
Refractive Index
1.3590
Melting Point
-94°C
Flash Point
-17°C(1°F)
Density
0.791
Safety Information
Packing Group
II
TSCA Listed
GHS Hazard statements
H225-H319-H336
Risk Statements
11-36-66-67
GHS Precautionary statements
P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
Safety Statements
9-16-26-46
European Hazard Symbols
Irritant Irritant (Xi)
Flammable Flammable (F)
GHS Pictograms
GHS02
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Hazard Class
3
UN Number
UN1090
RTECS
AL3150000
Product Information
Purity
99+%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Precursor of dimethyldioxirane, by reaction with K monopersulfate, and isolation in solution by low temperature distillation. For details, see: Chem. Ber., 124, 2377 (1991). It is an excellent reagent for rapid, stereospecific epoxidation of alkenes under mild conditions: J. Org. Chem., 50, 2847 (1985); Org. Synth. Coll., 9, 288 (1998). For improved work-up procedure allowing the possibility of more concentrated solutions or the isolation of acetone-free material, see: Tetrahedron Lett., 37, 3585 (1996). For biphasic, environmentally-friendly system (EtOAc-H2 O), see: Org. Process Res. Dev., 6, 407 (2002). Selective oxidation of phosphorus ylides occurs under mild conditions, providing a route to vicinal tricarbonyl derivatives: J. Org. Chem., 60, 8231 (1995). For conversion of ɑ-bromo-?-dicarbonyls to vicinal tricarbonyls, see: Tetrahedron Lett., 36, 7735 (1995). For formation of singlet oxygen by deoxygenation of heteroaromatic N-oxides, e.g. 4-diethylaminopyridine N-oxide, see: J. Chem. Soc., Chem.Commun., 1831 (1995). For reviews of dioxiranes, see: Acc. Chem. Res., 22, 205 (1989); Chem. Rev., 89, 1187 (1989).