Substance
ID:365892
Names and Identifiers
Synonyms
[双(三氟乙酰氧基)碘]苯PIFABTI[Bis(trifluoroacetoxy)iodo]benzeneIodobenzene I,I-bis(trifluoroacetate)I,I-双(三氟乙酸)碘苯
IUPAC Traditional name
phenyl[(trifluoroacetyl)oxy]-λ3-iodanyl 2,2,2-trifluoroacetate
IUPAC name
phenyl[(trifluoroacetyl)oxy]-λ3-iodanyl 2,2,2-trifluoroacetate
Registration numbers
CAS Number
MDL Number
Beilstein Number
PubChem SID
EC Number
Properties
Product Information
Purity
≥95.0% (AT)
Grade
purum
Linear Formula
(CF3CO2)2IC6H5
Physical Property
Melting Point
122-125 °C
121-125 °C(lit.)
Safety Information
GHS Signal Word
Warning
GHS Hazard statements
H315-H319-H335
European Hazard Symbols
Irritant (Xi)Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Risk Statements
36/37/38
German water hazard class
3
GHS Precautionary statements
P261-P305+P351+P338
Safety Statements
26-36
MSDS Link
Molecule Details
Other Notes
Reagent for dehydrogenation and oxidation reactions, review7; New reagent for the direct conversions of amides to amines (Hofmann-type rearrangement) and key substance for carboxyterminal peptide sequencing8; Smooth dethioacetalization to the carbonyls9
Application
Reactant or reagent for:
• Pummerer-like reactions1,2
• Chemoselective deprotection of dimethoxybenzyl ethers3
• Mediating oxidative cycloisomerization4,5
• Tosyloxylation of anilides6
Reagent for dehydrogenation and oxidation reactions, review7; New reagent for the direct conversions of amides to amines (Hofmann-type rearrangement) and key substance for carboxyterminal peptide sequencing8; Smooth dethioacetalization to the carbonyls9
Application
Reactant or reagent for:
• Pummerer-like reactions1,2
• Chemoselective deprotection of dimethoxybenzyl ethers3
• Mediating oxidative cycloisomerization4,5
• Tosyloxylation of anilides6
Molecular Spectra
No Data Available
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References
No Data Available
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