Substance
ID:365560
Names and Identifiers
IUPAC name
{1-[2-(diphenylphosphanyl)naphthalen-1-yl]naphthalen-2-yl}diphenylphosphane
IUPAC Traditional name
binap
Synonyms
(S)-(-)-(1,1′-Binaphthalene-2,2′-diyl)bis(diphenylphosphine)(S)-(-)-BINAP(S)-(-)-1,1′-联萘-2,2'-双二苯膦(S)-(-)-2,2′-双(二苯膦基)-1,1′-联萘(S)-(-)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene
Registration numbers
Beilstein Number
MDL Number
CAS Number
PubChem SID
Properties
Product Information
Optical Purity
enantiomeric ratio: ≥99.5:0.5 (HPLC)
Grade
puriss.
Linear Formula
[(C6H5)2PC10H6-]2
Physical Property
Melting Point
238-242 °C (dec.)
238-240 °C(lit.)
Optical Rotation
[α]20/D -239±5°, c = 0.3% in toluene
Safety Information
MSDS Link
Personal Protective Equipment
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class
3
Molecule Details
Application
Reactant involved in:
• Enantioselective and diastereoselective unpoled carbonyl allylation1
• Syntehsis of organophophine oxides as anittumor agents2
• SN2 halogenation of hydroxy groups3
• Synthesis of BINAP complexes4,5
• Studies of conformational flexibility of BINAP chelates6
Reactant involved in:
• Enantioselective and diastereoselective unpoled carbonyl allylation1
• Syntehsis of organophophine oxides as anittumor agents2
• SN2 halogenation of hydroxy groups3
• Synthesis of BINAP complexes4,5
• Studies of conformational flexibility of BINAP chelates6
Molecular Spectra
No Data Available
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References
No Data Available
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