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Substance
ID:363402
Structure
Similarity
Functional Group
Text
ID:99501
Trifluoroacetic anhydride
Sigma Aldrich
ID: 91720
Names and Identifiers
IUPAC Traditional name
trifluoroacetic anhydride
IUPAC name
trifluoroacetyl 2,2,2-trifluoroacetate
Synonyms
Trifluoroacetic anhydride
三氟乙酸酐
TFAA
Registration numbers
CAS Number
407-25-0
MDL Number
MFCD00000416
EC Number
206-982-9
Beilstein Number
746197
Properties
Safety Information
GHS Signal Word
Danger
Personal Protective Equipment
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
German water hazard class
2
European Hazard Symbols
Corrosive (C)
Risk Statements
14
-
20
-
35
-
52/53
Storage Temperature
2-8°C
UN Number
3265
RID/ADR
UN 3265 8/PG 1
Supplemental Hazard Statements
Reacts violently with water.
RTECS
AJ9800000
Safety Statements
26
-
36/37/39
-
43
-
45
-
61
Hazard Class
8
Packing Group
1
MSDS Link
Download link
GHS Hazard statements
H314
-
H332
-
H412
GHS Precautionary statements
P273
-
P280
-
P305+P351+P338
-
P310
Physical Property
Melting Point
-65 °C(lit.)
Boiling Point
39.5-40 °C(lit.)
Vapor Pressure
6.28 psi ( 20 °C)
Refractive Index
n20/D 1.3(lit.)
Density
1.511 g/mL at 20 °C(lit.)
Product Information
Grade
purum
Purity
≥99.0% (GC)
Linear Formula
(CF3CO)2O
Molecule Details
Other Notes
Powerful activator in the DMSO oxidation of alcohols to carbonyl compounds1,2
Molecular Spectra
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References
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