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Substance
ID:363254
Structure
Similarity
Functional Group
Text
ID:99501
Trifluoroacetic anhydride
Sigma Aldrich
ID: 91719
Names and Identifiers
IUPAC Traditional name
trifluoroacetic anhydride
IUPAC name
trifluoroacetyl 2,2,2-trifluoroacetate
Synonyms
Trifluoroacetic anhydride
三氟乙酸酐
TFAA
Registration numbers
CAS Number
407-25-0
MDL Number
MFCD00000416
EC Number
206-982-9
Beilstein Number
746197
PubChem SID
24889536
Properties
Safety Information
Packing Group
1
GHS Hazard statements
H314
-
H332
Personal Protective Equipment
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
Storage Temperature
2-8°C
Hazard Class
8
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
German water hazard class
2
Risk Statements
14
-
20
-
35
-
52/53
Supplemental Hazard Statements
Reacts violently with water.
European Hazard Symbols
Corrosive (C)
UN Number
3265
MSDS Link
Download link
RTECS
AJ9800000
Safety Statements
26
-
36/37/39
-
43
-
45
-
61
GHS Precautionary statements
P280
-
P305+P351+P338
-
P310
GHS Signal Word
Danger
RID/ADR
UN 3265 8/PG 1
Product Information
Derivatization reagent for
Acylations
Esterifications
Linear Formula
(CF3CO)2O
Grade
for GC derivatization
Purity
≥99.0% (GC)
Physical Property
Refractive Index
n20/D 1.3(lit.)
Melting Point
-65 °C(lit.)
Vapor Pressure
6.28 psi ( 20 °C)
Boiling Point
39.5-40 °C(lit.)
Density
1.511 g/mL at 20 °C(lit.)
Molecule Details
Other Notes
For the protection of prim. and sec. amines; derivatives are more volatile1
Molecular Spectra
No Data Available
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References
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Properties
Molecule Details
Molecular Spectra
References