Substance
ID:361174
Names and Identifiers
IUPAC name
(4R)-4-phenyl-1,3-oxazolidine-2-thione
IUPAC Traditional name
(4R)-4-phenyl-1,3-oxazolidine-2-thione
Synonyms
(R)-4-苯基噁唑烷-2-硫酮(R)-4-Phenyloxazolidine-2-thione
Properties
Physical Property
Optical Rotation
[α]/D -75±5°, c = 0.2 in chloroform
Product Information
Empirical Formula (Hill Notation)
C9H9NOS
Optical Purity
enantiomeric ratio: 97.0:3.0 (LC)
Purity
≥98.0%
Safety Information
MSDS Link
German water hazard class
3
Personal Protective Equipment
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Molecule Details
Application
A highly selective and efficient chiral auxiliary1 which can be directly reduced to its corresponding aldehyde and the chiral auxiliary by reductive cleavage with diisobutylaluminum hydride.2
Evans-Type Oxazolidinethione And Thiazolidinethione Auxiliaries
A highly selective and efficient chiral auxiliary1 which can be directly reduced to its corresponding aldehyde and the chiral auxiliary by reductive cleavage with diisobutylaluminum hydride.2
Evans-Type Oxazolidinethione And Thiazolidinethione Auxiliaries
Molecular Spectra
No Data Available
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References
No Data Available
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