Substance

ID:359654

Diisopropyl azodicarboxylate

Names and Identifiers
Synonyms
DIAD偶氮二甲酸二异丙酯Diisopropyl azodicarboxylateDiisopropyl azodiformate
IUPAC Traditional name
diisopropyl azodicarboxylate
IUPAC name
N-{[(propan-2-yloxy)carbonyl]imino}(propan-2-yloxy)formamide
Registration numbers
EC Number
MDL Number
Beilstein Number
PubChem SID
CAS Number
Properties
Product Information
Grade
technical
Linear Formula
(CH3)2CHOOCN=NCOOCH(CH3)2
Purity
≥94% (GC)
Safety Information
UN Number
3082
German water hazard class
1
RID/ADR
UN 3082 9/PG 3
MSDS Link
Risk Statements
36/38-51/53
Hazard Class
9
Safety Statements
26-60
Storage Temperature
2-8°C
Packing Group
3
European Hazard Symbols
Irritant Irritant (Xi)
Nature polluting Nature polluting (N)
Physical Property
Flash Point
106 °C
223 °F
Density
1.027 g/mL at 25 °C(lit.)
Boiling Point
75 °C/0.25 mmHg(lit.)
Refractive Index
n20/D 1.420
n20/D 1.420(lit.)
Molecule Details
Other Notes
Reagent used in the Mitsunobu reaction, reviews8,9
Application
Reactant for preparation of:
• Chromenes resembling classical cannabinoids1
• MK-3281 inhibitor of the hepatitis C virus NS5B polymerase2
• Norbornene-based guanidine-rich polymers as mimcs of cell-penetrating peptides (CPP)3
• Analogues of the Pseudomonas aeruginosa quorum-sensing molecule N-(3-Oxododecanoyl)-l-homoserine lactone with immunosuppressive but non-LasR-inducing properties4
• Acceptor-donor-acceptor organic dyes for dye-sensitized solar cells5
• 1,3-dioxane-2-carboxylic acid derivatives as PPARα/γ dual agonists6
• Hydrazinophosphonates and hydrazinobisphosphonates via Mitsunobu and Arbuzov-type multicomponent application of the Morrison-Brunn-Huisgen betaine7
Molecular Spectra
No Data Available
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References
No Data Available
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