Substance

ID:357457

Names and Identifiers
IUPAC Traditional name
methyl ethyl ketone peroxide
IUPAC name
2-[(2-hydroperoxybutan-2-yl)peroxy]butane-2-peroxol
Synonyms
Methyl ethyl ketone peroxide甲基乙基酮过氧化物2-Butanone peroxide2-过氧化丁酮Ethyl methyl ketone peroxide过氧化甲乙酮
Registration numbers
Beilstein Number
CAS Number
MDL Number
PubChem SID
Properties
Safety Information
GHS Pictograms
GHS02
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS05
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS09
Hazardous to the aquatic environment
Acute hazard, category1
Chronic hazard, categories 1,2
GHS08
Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A,1B,2
Carcinogenicity, categories 1A,1B,2
Reproductive toxicity, categories 1A,1B,2
Specific Target Organ Toxicity – Single exposure, categories 1,2
Specific Target Organ Toxicity – Repeated exposure, categories 1,2
Aspiration Hazard, category 1
GHS Hazard statements
H226-H242-H302-H314-H360Df-H410
European Hazard Symbols
Oxidising Oxidising (O)
Nature polluting Nature polluting (N)
Corrosive Corrosive (C)
GHS Precautionary statements
P201-P220-P273-P280-P305+P351+P338-P310
Personal Protective Equipment
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Class
5.2
German water hazard class
3
Risk Statements
7-22-34-50/53
GHS Signal Word
Danger
MSDS Link
RID/ADR
UN 3105 5.2
Safety Statements
3/7-14-26-36/37/39-45-61
Storage Temperature
2-8°C
UN Number
3105
Product Information
Linear Formula
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
Grade
technical
Contains
50-60% diacetone alcohol + phthalic acid ester as plasticizer
Physical Property
Flash Point
59 °C
138.2 °F
Refractive Index
n20/D 1.455
Density
1.053 g/mL at 20 °C(lit.)
Molecule Details
Application
Reactant for:
• Studies of the adiabatic runaway reaction of Me Et Ketone peroxide1
• Quantitation of metal ions in archaeological glass via abrasive stripping square-wave voltammetry2
• Imaging of hydrogen peroxide and hydrogen peroxide-scavenging substances by photon emission3
• Synthesis of oligonucleotides via phosphoramidite method4
• Oxidation of nucleoside phosphites into phosphates5
• Comparing the relative effectiveness of human plasma glutathione peroxidase as a catalyst for reduction of hydroperoxidases6Analyte for direct electrochemical catalystis of immobilized Hb in an ethanol-water mixture7
Molecular Spectra
No Data Available
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References
No Data Available
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