Substance

ID:357381

1,2-O-Isopropylidene-α-D-glucofuranose

Names and Identifiers
IUPAC name
(1R)-1-[(3aR,5R,6S,6aR)-6-hydroxy-2,2-dimethyl-tetrahydro-2H-furo[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol
Synonyms
Monoacetone glucose单丙酮葡萄糖1,2-O-Isopropylidene-α-D-glucofuranose1,2-O-异亚丙基-α-D-呋喃葡萄糖
IUPAC Traditional name
(1R)-1-[(3aR,5R,6S,6aR)-6-hydroxy-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol
Registration numbers
CAS Number
EC Number
MDL Number
Beilstein Number
Properties
Physical Property
Optical Rotation
[α]20/D -11.7±0.5°, c = 2% in H2O
Melting Point
158-161 °C
Product Information
Empirical Formula (Hill Notation)
C9H16O6
Grade
puriss.
Purity
≥98.5% (TLC)
Safety Information
MSDS Link
German water hazard class
3
Personal Protective Equipment
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage Temperature
2-8°C
Molecule Details
Other Notes
Partially protected D-glucofuranose, an important chiral building block. It can e.g. be selectively derivatized at the primary 6-OH group, or oxidatively cleaved to a pentodialdose derivative1; Direct transformation to the 5,6-anhydro compound (Mitsunobu reaction)2; Preparation of the 3,5-O-benzylidene derivative3
Molecular Spectra
No Data Available
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References
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