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Substance
ID:356582
Structure
Similarity
Functional Group
Text
ID:91087
2-Chloro-1,3,2-dioxaphospholane
Sigma Aldrich
ID: 24478
Names and Identifiers
IUPAC name
2-chloro-1,3,2-dioxaphospholane
IUPAC Traditional name
2-chloro-1,3,2-dioxaphospholane
Synonyms
2-Chloro-1,3,2-dioxaphospholane
2-氯-1,3,2-二氧磷杂环戊烷
环氯亚磷酸乙烯酯
Ethylene glycol chlorophosphite
Registration numbers
MDL Number
MFCD00014511
CAS Number
822-39-9
EC Number
212-499-4
Beilstein Number
506179
PubChem SID
24854703
Properties
Safety Information
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS Precautionary statements
P261
-
P280
-
P305+P351+P338
-
P310
RID/ADR
UN 3264 8/PG 2
Personal Protective Equipment
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
UN Number
3264
Hazard Class
8
GHS Signal Word
Danger
European Hazard Symbols
Corrosive (C)
Safety Statements
26
-
36/37/39
-
45
Supplemental Hazard Statements
Reacts violently with water.
GHS Hazard statements
H314
-
H335
German water hazard class
3
Risk Statements
14
-
34
-
37
MSDS Link
Download link
Packing Group
2
Storage Temperature
2-8°C
Product Information
Purity
≥97.0% (GC)
Empirical Formula (Hill Notation)
C2H4ClO2P
Grade
purum
Physical Property
Density
1.422 g/mL at 25 °C(lit.)
Flash Point
86 °C
186.8 °F
Refractive Index
n20/D 1.489(lit.)
n20/D 1.491
Boiling Point
62 °C/20 mmHg(lit.)
Molecule Details
Other Notes
Versatile cyclic chlorophosphite. It reacts with alcohols to the triester which can be oxidized or thionated 1,2; Derivatizing agent for analyzing carbohydrates by decoupled 31P spectroscopy3
Molecular Spectra
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References
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