Substance
ID:353489
Names and Identifiers
Synonyms
TriethylsilaneTriethylsilicon hydrideNSC 93579Triethylhydrosilane三乙基硅烷
IUPAC Traditional name
triethylsilane
IUPAC name
triethylsilane
Registration numbers
Beilstein Number
CAS Number
EC Number
MDL Number
Properties
Safety Information
GHS Signal Word
Danger
Safety Statements
9-16-29-33-61
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
European Hazard Symbols
Flammable (F)MSDS Link
German water hazard class
1
Personal Protective Equipment
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Risk Statements
11-52/53
UN Number
1993
GHS Precautionary statements
P210-P273
RID/ADR
UN 1993 3/PG 2
GHS Hazard statements
H225-H412
Packing Group
2
Hazard Class
3
Product Information
Purity
≥97.0% (GC)
Grade
purum
Linear Formula
(C2H5)3SiH
Physical Property
Boiling Point
107-108 °C(lit.)
Density
0.728 g/mL at 25 °C(lit.)
Flash Point
-3 °C
26.6 °F
Refractive Index
n20/D 1.412
n20/D 1.412(lit.)
Molecule Details
Other Notes
Reagent for the reduction of various functional groups (e.g. acyl halides to aldehydes, alkyl halides and secondary alcohols to hydrocarbons), review8,9,10; Silylating agent for alcohols, phenols, etc.11,12
Application
Catalyst for:
• Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain1
• Redox initiated cationic polymerization2,3
• Beckmann rearrangement of cyclododecanone oxime4
• Regioselective reductive coupling of enones and allenes5Catalyst reactivation after catalyst polymerization of styrene6Studies involving the prediction of organosilicon flash points7
Reagent for the reduction of various functional groups (e.g. acyl halides to aldehydes, alkyl halides and secondary alcohols to hydrocarbons), review8,9,10; Silylating agent for alcohols, phenols, etc.11,12
Application
Catalyst for:
• Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain1
• Redox initiated cationic polymerization2,3
• Beckmann rearrangement of cyclododecanone oxime4
• Regioselective reductive coupling of enones and allenes5Catalyst reactivation after catalyst polymerization of styrene6Studies involving the prediction of organosilicon flash points7
Molecular Spectra
No Data Available
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References
No Data Available
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