Substance

ID:353141

Ethyltriphenylphosphonium bromide

Names and Identifiers
IUPAC name
ethyltriphenylphosphanium bromide
IUPAC Traditional name
ethyltriphenylphosphanium bromide
Synonyms
Ethyltriphenylphosphonium bromideTEP乙基三苯基溴化膦
Registration numbers
Beilstein Number
EC Number
PubChem SID
CAS Number
MDL Number
Properties
Product Information
Linear Formula
[(C6H5)3P+C2H5]Br-
Grade
purum
Purity
≥98.5% (AT)
Safety Information
GHS Signal Word
Danger
GHS Hazard statements
H301-H411
GHS Pictograms
GHS09
Hazardous to the aquatic environment
Acute hazard, category1
Chronic hazard, categories 1,2
GHS06
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
GHS Precautionary statements
P273-P301+P310
European Hazard Symbols
Nature polluting Nature polluting (N)
Harmful Harmful (Xn)
RID/ADR
UN 3077 9/PG 3
Risk Statements
22-51/53
Safety Statements
61
Packing Group
3
MSDS Link
Hazard Class
9
German water hazard class
2
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
UN Number
3077
Physical Property
Flash Point
>200 °C
>392 °F
Melting Point
~205 °C
203-205 °C(lit.)
Molecule Details
Application
Reactant for synthesis of:
• D-amino acids from L-cysteine-derived thiazolidines1
• Leiodolide A via aldol reactions and Horner-Wadsworth-Emmons olefination2
• Cycloalkanoindolines via diastereoselective intramolecular inimo-ene reactions3
• WXYZA′ domain of maitotoxin using the coupling of key building blocks4Reactant for:
• Solid-state metathesis polycondensation to form alkyl-dipropenylthiophene monomers5
• Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization / lactonization cyclization reactions for synthesis of an ABC ring system6
Molecular Spectra
No Data Available
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References
No Data Available
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