Substance
ID:352792
Names and Identifiers
Synonyms
9-Fluorenylmethoxycarbonyl chlorideFMOC-Cl9-Fluorenylmethyl chloroformate氯甲酸-9-芴基甲酯Fmoc chloride芴甲氧羰酰氯9-芴甲氧羰酰氯
IUPAC name
9H-fluoren-9-ylmethyl chloroformate
IUPAC Traditional name
9H-fluoren-9-ylmethyl chloroformate
Registration numbers
CAS Number
MDL Number
Beilstein Number
EC Number
PubChem SID
Properties
Product Information
Empirical Formula (Hill Notation)
C15H11ClO2
Purity
≥98.0% (HPLC)
Grade
purum
Physical Property
Melting Point
62-64 °C(lit.)
61-63 °C
Safety Information
Personal Protective Equipment
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECS
LQ6250000
GHS Signal Word
Danger
Risk Statements
34
European Hazard Symbols
Corrosive (C)GHS Precautionary statements
P280-P305+P351+P338-P310
Safety Statements
26-36/37/39-45
UN Number
3261
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Hazard Class
8
MSDS Link
RID/ADR
UN 3261 8/PG 2
Storage Temperature
2-8°C
German water hazard class
3
GHS Hazard statements
H314
Packing Group
2
Molecule Details
Application
Reagent for derivatizing amino acids for HPLC amino acid analysis and for preparing N-Fmoc amino acids for solid-phase peptide synthesis.
Other Notes
For the introduction of the 9-fluorenylmethoxycarbonyl (Fmoc) amino-protecting group, which is stable towards acids and catalytic hydrogenation, but readily cleaved under mildly basic non-hydrolytic conditions1,2; Use of the Fmoc-group for the protection of hydroxy groups3; protection of amino groups in nucleotides4
Reagent for derivatizing amino acids for HPLC amino acid analysis and for preparing N-Fmoc amino acids for solid-phase peptide synthesis.
Other Notes
For the introduction of the 9-fluorenylmethoxycarbonyl (Fmoc) amino-protecting group, which is stable towards acids and catalytic hydrogenation, but readily cleaved under mildly basic non-hydrolytic conditions1,2; Use of the Fmoc-group for the protection of hydroxy groups3; protection of amino groups in nucleotides4
Molecular Spectra
No Data Available
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References
No Data Available
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