Substance

ID:346618

MolImageID:92030

(+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid

Sigma Aldrich
Names and Identifiers
IUPAC Traditional name
(2R,3R,11R,12R)-1,4,7,10,13,16-hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic acid
IUPAC name
(2R,3R,11R,12R)-1,4,7,10,13,16-hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic acid
Synonyms
(2R,3R,11R,12R)-1,4,7,10,13,16-Hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic acid(2R,3R,11R,12R)-1,4,7,10,13,16-六氧环十八烷-2,3,11,12-四羧酸(+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid(+)-(18-冠-6)-2,3,11,12-四羧酸
Registration numbers
MDL Number
MFCD00040514
CAS Number
61696-54-6
Beilstein Number
4240375
PubChem SID
24867945
Properties
Safety Information
MSDS Link
Download link
GHS Hazard statements
H315-H319-H335
GHS Pictograms
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
European Hazard Symbols
Irritant Irritant (Xi)
Risk Statements
36/37/38
Safety Statements
26-36
GHS Precautionary statements
P261-P305+P351+P338
German water hazard class
3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
GHS Signal Word
Warning
Physical Property
Melting Point
210-212 °C(lit.)
Optical Rotation
[α]20/D +62°, c = 1 in methanol
Product Information
Purity
97%
Empirical Formula (Hill Notation)
C16H24O14
Molecule Details
Application
Derived tetracarboxylic acid chloride of this crown ether reacts with meta- and para-xylylene diamines to form chiral captands in high yields.1 Used as a chiral selector in capillary zone electrophoresis for the separation of a variety of optically active amines.2 Synthesis of monoamides.3
Packaging
25, 100 mg in glass bottle
Molecular Spectra
No Data Available
Click here to submit data
References
No Data Available
Click here to submit data
Navigation