Substance
ID:346005
Names and Identifiers
IUPAC name
(iodomethyl)trimethylsilane
IUPAC Traditional name
(iodomethyl)trimethylsilane
Synonyms
(三甲基硅)甲基碘(Iodomethyl)trimethylsilane(Trimethylsilyl)methyl iodide碘甲基三甲基硅烷
Registration numbers
EC Number
CAS Number
MDL Number
Beilstein Number
PubChem SID
Properties
Physical Property
Density
1.443 g/mL at 25 °C(lit.)
Flash Point
84.2 °F
29 °C
Refractive Index
n20/D 1.491
n20/D 1.491(lit.)
Boiling Point
139-141 °C(lit.)
Safety Information
Packing Group
3
GHS Signal Word
Warning
German water hazard class
3
RID/ADR
UN 2924 3/PG 3
European Hazard Symbols
Irritant (Xi)GHS Hazard statements
H226-H315-H319-H335
Personal Protective Equipment
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Class
3
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Safety Statements
26-36
MSDS Link
GHS Precautionary statements
P261-P305+P351+P338
UN Number
2924
Risk Statements
10-36/37/38
Product Information
Linear Formula
(CH3)3SiCH2I
Purity
≥99.0% (GC)
Molecule Details
Other Notes
Starting material for the preparation of 2-(trimethylsilyl)ethyl-triphenylphosphonium iodide used for the synthesis of allyl silanes1,2; Used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions3
Packaging
5, 25 mL in glass bottle
Starting material for the preparation of 2-(trimethylsilyl)ethyl-triphenylphosphonium iodide used for the synthesis of allyl silanes1,2; Used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions3
Packaging
5, 25 mL in glass bottle
Molecular Spectra
No Data Available
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References
No Data Available
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