Substance
ID:345079
Names and Identifiers
IUPAC name
diphenyliodanium chloride
IUPAC Traditional name
diphenyliodanium chloride
Synonyms
DPINSC 134275Diphenyliodonium chloride二苯基碘酰氯
Registration numbers
EC Number
CAS Number
MDL Number
PubChem SID
Beilstein Number
Properties
Safety Information
Hazard Class
6.1
UN Number
2811
Packing Group
3
MSDS Link
Personal Protective Equipment
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
GHS Hazard statements
H301-H315-H319-H335
RTECS
NN6651666
Safety Statements
26-36
German water hazard class
3
GHS Signal Word
Danger
Risk Statements
25-36/37/38
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
European Hazard Symbols
Toxic (T)GHS Precautionary statements
P261-P301+P310-P305+P351+P338
RID/ADR
UN 2811 6.1/PG 3
Physical Property
Melting Point
233-235 °C (subl.)(lit.)
Product Information
Purity
≥98.0% (AT)
Linear Formula
(C6H5)2I+Cl-
Molecule Details
Other Notes
Reagent used for electrophilic phenylation, e.g. of malonates and dithiocarboxylates8,9,10
Packaging
5, 25 g in glass bottle
Application
Reactant for:
• Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts1
• Synthesis of acetylenic arylselenides2
• Sonogashira coupling reactions for the preparation of aryl alkynes3
• C-H functionalization for synthesis of (arylmethylene)oxindoles4
• Arylation of anilines5
• Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)6
• Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators7
Reagent used for electrophilic phenylation, e.g. of malonates and dithiocarboxylates8,9,10
Packaging
5, 25 g in glass bottle
Application
Reactant for:
• Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts1
• Synthesis of acetylenic arylselenides2
• Sonogashira coupling reactions for the preparation of aryl alkynes3
• C-H functionalization for synthesis of (arylmethylene)oxindoles4
• Arylation of anilines5
• Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)6
• Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators7
Molecular Spectra
No Data Available
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References
No Data Available
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