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Substance
ID:344768
Structure
Similarity
Functional Group
Text
ID:74420
α,α-Diphenyl-N-methyl-L-prolinol
Sigma Aldrich
ID: 43119
Names and Identifiers
Synonyms
(S)-α,α-Diphenyl-N-methyl-2-pyrrolidinemethanol
α,α-二苯基-N-甲基-L-脯氨醇
α,α-Diphenyl-N-methyl-L-prolinol
(S)-α,α-二苯基-N-甲基-2-吡咯烷甲醇
IUPAC Traditional name
[(2S)-1-methylpyrrolidin-2-yl]diphenylmethanol
IUPAC name
[(2S)-1-methylpyrrolidin-2-yl]diphenylmethanol
Registration numbers
MDL Number
MFCD00145245
CAS Number
110529-22-1
Beilstein Number
4749387
PubChem SID
24866974
Properties
Safety Information
GHS Signal Word
Warning
MSDS Link
Download link
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Safety Statements
26
-
36
GHS Precautionary statements
P261
-
P305+P351+P338
German water hazard class
3
GHS Hazard statements
H315
-
H319
-
H335
European Hazard Symbols
Irritant (Xi)
Risk Statements
36/37/38
Product Information
Purity
≥96.0% (sum of enantiomers, GC)
Empirical Formula (Hill Notation)
C18H21NO
Physical Property
Optical Rotation
[α]20/D +55±3°, c = 1% in chloroform stab. with amylenes
Melting Point
66-72 °C
Molecule Details
Other Notes
Ligand employed in the enantioselective addition of dialkylzincs to carbonyls1,2,3,4
Packaging
250 mg in glass bottle
Molecular Spectra
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References
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