Substance
ID:343334
Names and Identifiers
IUPAC Traditional name
diethyl(1,1,2,3,3,3-hexafluoropropyl)amine
IUPAC name
diethyl(1,1,2,3,3,3-hexafluoropropyl)amine
Synonyms
Ishikawa’s ReagentIshikawa 试剂N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamineN,N-二乙基-1,1,2,3,3,3-六氟丙胺
Properties
Physical Property
Flash Point
40 °C
104 °F
Density
1.230 g/mL at 25 °C(lit.)
Refractive Index
n20/D 1.3460(lit.)
Boiling Point
56-57 °C(lit.)
Safety Information
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS Precautionary statements
P280-P305+P351+P338-P310
Risk Statements
10-34
Hazard Class
8
Packing Group
2
GHS Hazard statements
H226-H314
Personal Protective Equipment
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
German water hazard class
3
GHS Signal Word
Danger
UN Number
2920
European Hazard Symbols
Corrosive (C)RID/ADR
UN 2920 8/PG 2
Safety Statements
16-26-36/37/39-45
MSDS Link
Product Information
Linear Formula
CF3CHFCF2N(C2H5)2
Molecule Details
Application
Demonstrates utility in fluorination.7
Displays the ability to insert a fluoro(trifluoromethyl) methylene moiety in unsaturated alcohols.
Reactant for:
• Friedel-Crafts type arylation of hydrofluorocarbons1
• Microbial hydroxylation of antibiotics2
• Electrochemical fluorination of trialkylamines and tetraalkylammonium salts3
• Fluorination of pyrethroides4Reactant for synthesis of:
• γ-Hydroxy-α-fluoro-α-trifluoromethylcarboxamide5
• Florfenicol and thiamphenicol6
Packaging
25 g in glass bottle
General description
GC analysis includes Et2NCF=CFCF3 (two isomers), both of which are active fluorinating agents.
Demonstrates utility in fluorination.7
Displays the ability to insert a fluoro(trifluoromethyl) methylene moiety in unsaturated alcohols.
Reactant for:
• Friedel-Crafts type arylation of hydrofluorocarbons1
• Microbial hydroxylation of antibiotics2
• Electrochemical fluorination of trialkylamines and tetraalkylammonium salts3
• Fluorination of pyrethroides4Reactant for synthesis of:
• γ-Hydroxy-α-fluoro-α-trifluoromethylcarboxamide5
• Florfenicol and thiamphenicol6
Packaging
25 g in glass bottle
General description
GC analysis includes Et2NCF=CFCF3 (two isomers), both of which are active fluorinating agents.
Molecular Spectra
No Data Available
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References
No Data Available
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