Substance

ID:341313

Names and Identifiers
IUPAC name
dioxoplatinum
IUPAC Traditional name
adams' catalyst
Synonyms
platinum dioxideplatinic oxide二氧化铂NSC 402624Adam’s catalyst亚当斯催化剂Platinum(IV) oxide
Registration numbers
EC Number
CAS Number
MDL Number
PubChem SID
Properties
Safety Information
UN Number
1479
RID/ADR
UN 1479 5.1/PG 2
GHS Hazard statements
H272-H319
GHS Precautionary statements
P220-P305+P351+P338
GHS Signal Word
Danger
Packing Group
2
German water hazard class
2
GHS Pictograms
GHS03
Oxidizing gases, category 1
Oxidizing liquids, categories 1,2,3
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Risk Statements
8-36
Safety Statements
26
European Hazard Symbols
Irritant Irritant (Xi)
Oxidising Oxidising (O)
MSDS Link
Personal Protective Equipment
Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Class
5.1
Product Information
Surface Area
≥60 m2/g
Linear Formula
PtO2
Compostion
Pt, 81-83%
Physical Property
Melting Point
450 °C(lit.)
Molecule Details
Frequently Asked Questions
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Application
Catalyst for hydrogenation of various functional groups with minimal hydrogenolysis problems; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols.
Catalyst for:
• Hydrohydrazination reactions1
• Oxidation of sugars2
• Low-temperature oxidation of carbon monoxide3
• Oxygen reduction reaction4
• Hydrogenation reactions5
• Hydrogenolysis of the cyclopropyl group into an isopropyl group6
• Hydroxycyclopropanation reactions7
Packaging
1, 5 g in glass bottle
250 mg in glass bottle
Molecular Spectra
No Data Available
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References
No Data Available
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