Substance
ID:340370
Names and Identifiers
IUPAC name
diiodosamarium
IUPAC Traditional name
samarium(II) iodide
Synonyms
Samarium(II) iodide solution碘化钐(II) 溶液
Properties
Physical Property
Density
0.922 g/mL at 25 °C
Apperance
liquid
Flash Point
-2.2 °F
-19 °C
Safety Information
Safety Statements
16-26
GHS Precautionary statements
P210
RID/ADR
UN 2056 3/PG 2
German water hazard class
3
Packing Group
2
GHS Hazard statements
H225
European Hazard Symbols
Flammable (F)
Irritant (Xi)MSDS Link
Personal Protective Equipment
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Risk Statements
11-19-36/37
GHS Signal Word
Danger
UN Number
2056
Hazard Class
3
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Product Information
Linear Formula
SmI2
Concentration
0.1 M in THF
Contains
samarium chips as stabilizer
Molecule Details
Application
A promoter of reactions involving samarium ketyl aryl cyclizations.1
An effective single-electron reducing agent for the promotion of ketone-olefin and pinacol coupling reactions under mild conditions. Often both intramolecular and intermolecular couplings proceed in a highly stereoselective fashion. Starting material for the synthesis of new heteroleptic samarium aryloxide/cyclopentadienide complexes.
Packaging
25, 4×25, 100, 800 mL in Sure/Seal™
A promoter of reactions involving samarium ketyl aryl cyclizations.1
An effective single-electron reducing agent for the promotion of ketone-olefin and pinacol coupling reactions under mild conditions. Often both intramolecular and intermolecular couplings proceed in a highly stereoselective fashion. Starting material for the synthesis of new heteroleptic samarium aryloxide/cyclopentadienide complexes.
Packaging
25, 4×25, 100, 800 mL in Sure/Seal™
Molecular Spectra
No Data Available
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References
No Data Available
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