Substance

ID:338157

4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene

Names and Identifiers
IUPAC Traditional name
xantphos
IUPAC name
[5-(diphenylphosphanyl)-9,9-dimethyl-9H-xanthen-4-yl]diphenylphosphane
Synonyms
Xantphos4,5-双(二苯基膦基)-9,9-二甲基呫吨4,5-双二苯基膦-9,9-二甲基氧杂蒽4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
Registration numbers
CAS Number
MDL Number
PubChem SID
Properties
Physical Property
Ligand For
C-X Bond Formation
Stille Coupling
Buchwald-Hartwig Cross Coupling Reaction
Hydroformylations
Miyaura Borylation Reaction
Suzuki-Miyaura Coupling
Melting Point
224-228 °C(lit.)
Safety Information
Personal Protective Equipment
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class
3
MSDS Link
Product Information
Empirical Formula (Hill Notation)
C39H32OP2
Purity
97%
Molecule Details
Application
Ligand used in a synthesis of heterocycles by palladium-catalyzed C-N cross coupling of 3-bromothiophenes with 2-aminopyridines.1 Also used in a ruthenium-catalyzed alkylation of active methylene compounds with alcohols.2
Metal chelating ligand for catalysis.
Packaging
1, 5, 25 g in glass bottle
Molecular Spectra
No Data Available
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References
No Data Available
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