Substance
ID:336779
Names and Identifiers
IUPAC name
ethyl 2-(diethoxyphosphoryl)-2-fluoroacetate
IUPAC Traditional name
ethyl 2-(diethoxyphosphoryl)-2-fluoroacetate
Synonyms
2-Fluoro-2-phosphonoacetic acid triethyl ester2-氟-2-膦酰基乙酸三乙酯Ethyl diethylphosphonofluoroacetateTriethyl 2-fluoro-2-phosphonoacetateDiethyl [(ethoxycarbonyl)fluoromethyl]phosphonate
Registration numbers
CAS Number
PubChem SID
Beilstein Number
MDL Number
Properties
Physical Property
Flash Point
163.4 °F
73 °C
Refractive Index
n20/D 1.425(lit.)
Boiling Point
75 °C/0.01 mmHg(lit.)
Density
1.194 g/mL at 25 °C(lit.)
Safety Information
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Safety Statements
26-36
European Hazard Symbols
Irritant (Xi)GHS Hazard statements
H315-H319-H335
Personal Protective Equipment
Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Signal Word
Warning
GHS Precautionary statements
P261-P305+P351+P338
German water hazard class
3
MSDS Link
Risk Statements
36/37/38
Product Information
Purity
96%
Linear Formula
(C2H5O)2P(O)CH(F)CO2C2H5
Molecule Details
Packaging
1, 5 g in glass bottle
Application
Reactant for:
• Diels-Alder reactions1
• Biosynthesis of terpene2
• Stereoselective synthesis of unsaturated esters, fluorides and nitriles from the reactions of aldehydes and ketones using Wadsworth-Emmons phosphonates3
• Synthesis of quinolones4
• Horner-Wadsworth-Emmons asymmetric hydration5
• Addition reactions and the subsequent application to click chemistry6
• Asymmetric intermolecular Stetter reactions7
1, 5 g in glass bottle
Application
Reactant for:
• Diels-Alder reactions1
• Biosynthesis of terpene2
• Stereoselective synthesis of unsaturated esters, fluorides and nitriles from the reactions of aldehydes and ketones using Wadsworth-Emmons phosphonates3
• Synthesis of quinolones4
• Horner-Wadsworth-Emmons asymmetric hydration5
• Addition reactions and the subsequent application to click chemistry6
• Asymmetric intermolecular Stetter reactions7
Molecular Spectra
No Data Available
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References
No Data Available
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