Substance
ID:336406
Names and Identifiers
IUPAC name
tris(trifluoromethanesulfonyloxy)hafnio trifluoromethanesulfonate
IUPAC Traditional name
tris(trifluoromethanesulfonyloxy)hafnio trifluoromethanesulfonate
Synonyms
Hf(OTf)4Hafnium(IV) trifluoromethanesulfonate hydrate三氟甲磺酸铪 水合物三氟甲烷磺酸铪(IV)Hafnium(IV) triflate
Properties
Safety Information
MSDS Link
German water hazard class
3
GHS Signal Word
Warning
European Hazard Symbols
Irritant (Xi)GHS Precautionary statements
P261-P305+P351+P338
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
GHS Hazard statements
H315-H319-H335
Safety Statements
26-36
Risk Statements
36/37/38
Product Information
Linear Formula
(CF3SO3)4Hf
Physical Property
Melting Point
>350 °C(lit.)
Molecule Details
Application
Excellent and recyclable catalyst for the mononitration of o-nitrotoluene.8
Catalyst for:
• Homogeneous methoxycarbonylation and hydrocarboxylation reactions of phenylacetylene1
• Direct Friedel-Crafts reactions of chromene hemiacetals2
• Aminomethylation reactions under Lewis acidic conditions3
• Prins-type cyclization reactions4
• Direct polycondensation of lactic acid5
• Cationic benzylation reactions6
• Chemoselective thioacetalization and transthioacetalization of carbonyl compounds7
Packaging
1 g in glass bottle
Excellent and recyclable catalyst for the mononitration of o-nitrotoluene.8
Catalyst for:
• Homogeneous methoxycarbonylation and hydrocarboxylation reactions of phenylacetylene1
• Direct Friedel-Crafts reactions of chromene hemiacetals2
• Aminomethylation reactions under Lewis acidic conditions3
• Prins-type cyclization reactions4
• Direct polycondensation of lactic acid5
• Cationic benzylation reactions6
• Chemoselective thioacetalization and transthioacetalization of carbonyl compounds7
Packaging
1 g in glass bottle
Molecular Spectra
No Data Available
Click here to submit data
References
No Data Available
Click here to submit data