Substance
ID:336283
Names and Identifiers
Synonyms
DIAD偶氮二甲酸二异丙酯Diisopropyl azodicarboxylateDiisopropyl azodiformate
IUPAC Traditional name
diisopropyl azodicarboxylate
IUPAC name
N-{[(propan-2-yloxy)carbonyl]imino}(propan-2-yloxy)formamide
Registration numbers
MDL Number
Beilstein Number
CAS Number
PubChem SID
Properties
Safety Information
GHS Pictograms
Hazardous to the aquatic environment
Acute hazard, category1
Chronic hazard, categories 1,2
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A,1B,2
Carcinogenicity, categories 1A,1B,2
Reproductive toxicity, categories 1A,1B,2
Specific Target Organ Toxicity – Single exposure, categories 1,2
Specific Target Organ Toxicity – Repeated exposure, categories 1,2
Aspiration Hazard, category 1
RID/ADR
UN 3082 9/PG 3
GHS Signal Word
Warning
Risk Statements
36/37/38-40-48/20/22-51/53
German water hazard class
2
GHS Precautionary statements
P261-P273-P281-P305+P351+P338
UN Number
3082
GHS Hazard statements
H315-H319-H335-H351-H373-H411
MSDS Link
Safety Statements
26-36/37-61
Storage Temperature
2-8°C
Packing Group
3
European Hazard Symbols
Nature polluting (N)
Harmful (Xn)Personal Protective Equipment
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Class
9
Product Information
Purity
98%
Impurities
≤2% dichloromethane
Linear Formula
(CH3)2CHOOCN=NCOOCH(CH3)2
Physical Property
Boiling Point
75 °C/0.25 mmHg(lit.)
Flash Point
222.8 °F
106 °C
Refractive Index
n20/D 1.420(lit.)
Density
1.027 g/mL at 25 °C(lit.)
Molecule Details
General description
Reacted with dioxaphosphorinanes and iron catalyst to generate rearranged phosphonium ylide products.8
Packaging
25, 100 g in poly bottle
5 g in glass bottle
Application
Reactant for preparation of:
• Chromenes resembling classical cannabinoids1
• MK-3281 inhibitor of the hepatitis C virus NS5B polymerase2
• Norbornene-based guanidine-rich polymers as mimcs of cell-penetrating peptides (CPP)3
• Analogues of the Pseudomonas aeruginosa quorum-sensing molecule N-(3-Oxododecanoyl)-l-homoserine lactone with immunosuppressive but non-LasR-inducing properties4
• Acceptor-donor-acceptor organic dyes for dye-sensitized solar cells5
• 1,3-dioxane-2-carboxylic acid derivatives as PPARα/γ dual agonists6
• Hydrazinophosphonates and hydrazinobisphosphonates via Mitsunobu and Arbuzov-type multicomponent application of the Morrison-Brunn-Huisgen betaine7
Reacted with dioxaphosphorinanes and iron catalyst to generate rearranged phosphonium ylide products.8
Packaging
25, 100 g in poly bottle
5 g in glass bottle
Application
Reactant for preparation of:
• Chromenes resembling classical cannabinoids1
• MK-3281 inhibitor of the hepatitis C virus NS5B polymerase2
• Norbornene-based guanidine-rich polymers as mimcs of cell-penetrating peptides (CPP)3
• Analogues of the Pseudomonas aeruginosa quorum-sensing molecule N-(3-Oxododecanoyl)-l-homoserine lactone with immunosuppressive but non-LasR-inducing properties4
• Acceptor-donor-acceptor organic dyes for dye-sensitized solar cells5
• 1,3-dioxane-2-carboxylic acid derivatives as PPARα/γ dual agonists6
• Hydrazinophosphonates and hydrazinobisphosphonates via Mitsunobu and Arbuzov-type multicomponent application of the Morrison-Brunn-Huisgen betaine7
Molecular Spectra
No Data Available
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References
No Data Available
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