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Substance
ID:335151
Structure
Similarity
Functional Group
Text
ID:70652
Dess-Martin periodinane
Sigma Aldrich
ID: 274623
Names and Identifiers
IUPAC Traditional name
dess-martin periodinane
Synonyms
Dess-Martin periodinane
1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one
1,1,1-三(乙酰氧基)-1,1-二氢-1,2-苯碘酰-3-(1H)-酮
戴斯-马丁氧化剂
IUPAC name
1,1-bis(acetyloxy)-3-oxo-3H-1λ
5
,2-benziodaoxol-1-yl acetate
Registration numbers
CAS Number
87413-09-0
MDL Number
MFCD00130127
PubChem SID
24856593
Properties
Product Information
Purity
97%
Empirical Formula (Hill Notation)
C13H13IO8
Safety Information
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Oxidizing gases, category 1
Oxidizing liquids, categories 1,2,3
Risk Statements
8
-
20/21/22
-
36/37/38
-
44
European Hazard Symbols
Oxidising (O)
Harmful (Xn)
GHS Signal Word
Warning
GHS Precautionary statements
P220
-
P261
-
P280
-
P305+P351+P338
Supplemental Hazard Statements
Risk of explosion if heated under confinement.
MSDS Link
Download link
German water hazard class
3
Safety Statements
26
-
36
GHS Hazard statements
H272
-
H302
-
H312
-
H315
-
H319
-
H332
-
H335
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Storage Temperature
-20°C
Physical Property
Melting Point
130-133 °C(lit.)
Molecule Details
Application
Oxidizing agent for 1° and 2° alcohols to aldehydes and ketones.1,2
Used for the oxidation of hydroxychlorins to chlorin-α-diones and tetraones.
Packaging
1, 5, 25, 50, 250 g in glass bottle
Molecular Spectra
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References
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Properties
Molecule Details
Molecular Spectra
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