Substance

ID:335151

Dess-Martin periodinane

Names and Identifiers
IUPAC Traditional name
dess-martin periodinane
Synonyms
Dess-Martin periodinane1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one1,1,1-三(乙酰氧基)-1,1-二氢-1,2-苯碘酰-3-(1H)-酮戴斯-马丁氧化剂
IUPAC name
1,1-bis(acetyloxy)-3-oxo-3H-1λ5,2-benziodaoxol-1-yl acetate
Registration numbers
CAS Number
MDL Number
PubChem SID
Properties
Product Information
Purity
97%
Empirical Formula (Hill Notation)
C13H13IO8
Safety Information
GHS Pictograms
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS03
Oxidizing gases, category 1
Oxidizing liquids, categories 1,2,3
Risk Statements
8-20/21/22-36/37/38-44
European Hazard Symbols
Oxidising Oxidising (O)
Harmful Harmful (Xn)
GHS Signal Word
Warning
GHS Precautionary statements
P220-P261-P280-P305+P351+P338
Supplemental Hazard Statements
Risk of explosion if heated under confinement.
MSDS Link
German water hazard class
3
Safety Statements
26-36
GHS Hazard statements
H272-H302-H312-H315-H319-H332-H335
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Storage Temperature
-20°C
Physical Property
Melting Point
130-133 °C(lit.)
Molecule Details
Application
Oxidizing agent for 1° and 2° alcohols to aldehydes and ketones.1,2
Used for the oxidation of hydroxychlorins to chlorin-α-diones and tetraones.
Packaging
1, 5, 25, 50, 250 g in glass bottle
Molecular Spectra
No Data Available
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References
No Data Available
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