Substance

ID:334964

N-Fluorobenzenesulfonimide

Names and Identifiers
IUPAC name
N-(benzenesulfonyl)-S-phenylfluoranesulfonamido
IUPAC Traditional name
N-(benzenesulfonyl)-S-phenylfluoranesulfonamido
Synonyms
N-FluorodibenzenesulfonimideN-氟苯磺酰亚胺N-氟代双苯磺酰胺NFSIN-氟二苯磺酰胺N-FluorobenzenesulfonimideN-Fluorodi(benzenesulfonyl)amine
Registration numbers
CAS Number
MDL Number
Beilstein Number
PubChem SID
Properties
Safety Information
Safety Statements
26
GHS Signal Word
Warning
MSDS Link
German water hazard class
3
GHS Pictograms
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS Hazard statements
H315-H319-H335
European Hazard Symbols
Irritant Irritant (Xi)
Risk Statements
36/37/38
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements
P261-P305+P351+P338
Product Information
Purity
97%
Linear Formula
(C6H5SO2)2NF
Physical Property
Melting Point
110 °C (dec.)(lit.)
Molecule Details
Application
Reagent employed in a palladium-catalyzed enantioselective fluorination of t-butoxycarbonyl lactones and lactams.1 Also used in the electrophilic difluorination of dihalopyridines with butyl lithium2 and in the direct conversion of alcohols to dibenzenesulfonamides with triphenylphosphine.3
Stable, easy-to-handle, crystalline material which readily transfers F+ to enolates and carbanions.
Packaging
5, 500 g in poly bottle
Molecular Spectra
No Data Available
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References
No Data Available
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