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Substance
ID:332906
Structure
Similarity
Functional Group
Text
ID:8349
4-Acetylphenylboronic acid
Sigma Aldrich
ID: 470821
Names and Identifiers
IUPAC name
(4-acetylphenyl)boronic acid
IUPAC Traditional name
4-acetylphenylboronic acid
Synonyms
4-Acetylphenylboronic acid
4-乙酰苯基硼酸
Registration numbers
CAS Number
149104-90-5
PubChem SID
24870686
MDL Number
MFCD01074667
Properties
Safety Information
GHS Precautionary statements
P261
-
P305+P351+P338
Safety Statements
26
-
36
Risk Statements
36/37/38
German water hazard class
3
GHS Signal Word
Warning
GHS Hazard statements
H315
-
H319
-
H335
MSDS Link
Download link
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
European Hazard Symbols
Irritant (Xi)
Product Information
Linear Formula
CH3COC6H4B(OH)2
Physical Property
Melting Point
240-244 °C(lit.)
Molecule Details
Other Notes
Contains varying amounts of anhydride
Packaging
5, 25 g in glass bottle
Application
Reactant involved in:
• Palladium-catalyzed decarboxylative coupling1
• Copper-catalyzed hydroxylation2
• Palladium-catalyzed Suzuki-Miyaura cross-coupling3
• Cross-coupling with α-bromocarbonyl compounds4
• Oxidation catalyzed by Baeyer-Villiger monooxygenases5
• 1,5-substitution reactions6
Molecular Spectra
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References
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