Substance
ID:331495
Names and Identifiers
IUPAC Traditional name
tetrapropylammonium rutheniumoylolate
IUPAC name
tetrapropylazanium rutheniumoylolate
Synonyms
Tetrapropylammonium perruthenate四丙基高钌酸铵TPAP
Properties
Product Information
Purity
97%
Linear Formula
(CH3CH2CH2)4NRuO4
Safety Information
European Hazard Symbols
Oxidising (O)
Irritant (Xi)GHS Precautionary statements
P220-P261-P305+P351+P338
German water hazard class
3
GHS Signal Word
Danger
UN Number
1479
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Oxidizing gases, category 1
Oxidizing liquids, categories 1,2,3
Personal Protective Equipment
Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RID/ADR
UN 1479 5.1/PG 2
Risk Statements
5-8-36/37/38
GHS Hazard statements
H272-H315-H319-H335
MSDS Link
Hazard Class
5.1
Safety Statements
17-26-36
Packing Group
2
Physical Property
Melting Point
~160 °C (dec.)(lit.)
Molecule Details
Application
A soluble, nonvolatile, air-stable, mild oxidant which can be used either stoichiometrically or catalytically with a suitable co-oxidant.
Oxidant used to convert N,N′-dihydroxyimidazolidines to nitronyl nitroxide free radicals.1 Oxidation of hydroxyl-substituted tri-n-butylammonium trifluoroborates to aldehydes and ketones without concomitant cleavage of the carbon-boron bond.2,3
Packaging
1 g in glass bottle
250 mg in glass bottle
A soluble, nonvolatile, air-stable, mild oxidant which can be used either stoichiometrically or catalytically with a suitable co-oxidant.
Oxidant used to convert N,N′-dihydroxyimidazolidines to nitronyl nitroxide free radicals.1 Oxidation of hydroxyl-substituted tri-n-butylammonium trifluoroborates to aldehydes and ketones without concomitant cleavage of the carbon-boron bond.2,3
Packaging
1 g in glass bottle
250 mg in glass bottle
Molecular Spectra
No Data Available
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References
No Data Available
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