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Substance
ID:328578
Structure
Similarity
Functional Group
Text
ID:74863
Ethyl (triphenylphosphoranylidene)pyruvate
Sigma Aldrich
ID: 518093
Names and Identifiers
Synonyms
NSC 647346
[(Carboxycarbonyl)methylene]triphenylphosphorane ethyl ester
(三苯基膦)丙酮酸乙酯
Ethyl (triphenylphosphoranylidene)pyruvate
2-Ethoxycarbonyl-2-oxoethylidenetriphenylphosphorane
IUPAC name
ethyl 2-oxo-3-(triphenyl-λ
5
-phosphanylidene)propanoate
IUPAC Traditional name
ethyl 2-oxo-3-(triphenyl-λ
5
-phosphanylidene)propanoate
Registration numbers
MDL Number
MFCD00208428
CAS Number
13321-61-4
PubChem SID
24873999
Properties
Safety Information
German water hazard class
3
Personal Protective Equipment
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
MSDS Link
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Product Information
Linear Formula
(C6H5)3P=CHCOCO2C2H5
Purity
95%
Physical Property
Melting Point
175 °C (dec.)(lit.)
Molecule Details
Packaging
25 g in glass bottle
Application
Reactant for:
• Wittig condensation1
• Chemoenzymic preparation of hexafluoroleucine and tetrafluoroleucine2Reactant for synthesis of:
• Ahiral and chiral cyclic dehydro-α-amino acid derivatives through nucleophilic addition3
• Peptidyl α-keto-based inhibitors of cruzain4
• Deoxyfluoro-L-arabinofuranosyl triazole nucleoside derivatives with antiviral activity5
• Anti-human immunodificiency virus analogs6
Molecular Spectra
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References
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Properties
Molecule Details
Molecular Spectra
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