Substance
ID:327113
Names and Identifiers
IUPAC name
diethyl {[methoxy(methyl)carbamoyl]methyl}phosphonate
IUPAC Traditional name
diethyl [methoxy(methyl)carbamoyl]methylphosphonate
Synonyms
Diethyl (N-methoxy-N-methylcarbamoylmethyl)phosphonateN-甲氧基-N-甲羰基甲基膦酸二乙酯N-Methoxy-N-methyl-phosphonoacetamide diethyl esterDiethyl N-methoxy-N-methylphosphonoacetamideN-Methoxy-N-methyl-2-(diethyl phosphono)acetamideDiethylphosphonoacetic acid N-methyl-N-methoxyamide
Registration numbers
CAS Number
MDL Number
Beilstein Number
PubChem SID
Properties
Product Information
Purity
96%
Linear Formula
CH3ON(CH3)COCH2P(O)(OC2H5)2
Physical Property
Flash Point
230 °F
110 °C
Density
1.163 g/mL at 25 °C(lit.)
Refractive Index
n20/D 1.455(lit.)
Boiling Point
90 °C/17 mmHg(lit.)
Safety Information
European Hazard Symbols
Irritant (Xi)MSDS Link
Safety Statements
26-36
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS Signal Word
Warning
GHS Hazard statements
H315-H319-H335
German water hazard class
3
Risk Statements
36/37/38
Personal Protective Equipment
Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements
P261-P305+P351+P338
Molecule Details
Application
Wittig carbonylating reagent.7
Reactant for:
• Preparation of ring-expanded bryostatin analogs as antitumor agents1
• Asymmertic synthesis of pinnatoxins A and G via diastereoselective Ireland-Claisen rearrangement, ring closing metathesis, and cyclization2
• Rh2(II)-catalyzed nitro-group migration reactions3
• Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition reactions4
• Stereoselective synthesis of (+)-polyrhacitide A via aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction as the key steps5
• Preparation of substituted furans via olefin cross-metathesis6
Packaging
1, 5 g in glass bottle
Wittig carbonylating reagent.7
Reactant for:
• Preparation of ring-expanded bryostatin analogs as antitumor agents1
• Asymmertic synthesis of pinnatoxins A and G via diastereoselective Ireland-Claisen rearrangement, ring closing metathesis, and cyclization2
• Rh2(II)-catalyzed nitro-group migration reactions3
• Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition reactions4
• Stereoselective synthesis of (+)-polyrhacitide A via aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction as the key steps5
• Preparation of substituted furans via olefin cross-metathesis6
Packaging
1, 5 g in glass bottle
Molecular Spectra
No Data Available
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References
No Data Available
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