Substance
ID:326251
Names and Identifiers
IUPAC name
dioxoplatinum
IUPAC Traditional name
adams' catalyst
Synonyms
platinum dioxideplatinic oxide二氧化铂NSC 402624Adam’s catalyst亚当斯催化剂Platinum(IV) oxide
Properties
Physical Property
Melting Point
450 °C(lit.)
Safety Information
Safety Statements
26
UN Number
1479
German water hazard class
2
GHS Pictograms
Oxidizing gases, category 1
Oxidizing liquids, categories 1,2,3
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
European Hazard Symbols
Oxidising (O)
Irritant (Xi)Packing Group
2
GHS Signal Word
Danger
GHS Hazard statements
H272-H319
GHS Precautionary statements
P220-P305+P351+P338
Hazard Class
5.1
Personal Protective Equipment
Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
MSDS Link
RID/ADR
UN 1479 5.1/PG 2
Risk Statements
8-36
Product Information
Compostion
Pt, 80-85%
Linear Formula
PtO2
Impurities
iron, low
Surface Area
≥75 m2/g
Molecule Details
Application
Catalyst for hydrogenation of various functional groups; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols.
Catalyst for:
• Hydrohydrazination reactions1
• Oxidation of sugars2
• Low-temperature oxidation of carbon monoxide3
• Oxygen reduction reaction4
• Hydrogenation reactions5
• Hydrogenolysis of the cyclopropyl group into an isopropyl group6
• Hydroxycyclopropanation reactions7
General description
Prepared by Adams′ nitrate fusion method.
Packaging
1, 5 g in glass bottle
250 mg in glass bottle
Catalyst for hydrogenation of various functional groups; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols.
Catalyst for:
• Hydrohydrazination reactions1
• Oxidation of sugars2
• Low-temperature oxidation of carbon monoxide3
• Oxygen reduction reaction4
• Hydrogenation reactions5
• Hydrogenolysis of the cyclopropyl group into an isopropyl group6
• Hydroxycyclopropanation reactions7
General description
Prepared by Adams′ nitrate fusion method.
Packaging
1, 5 g in glass bottle
250 mg in glass bottle
Molecular Spectra
No Data Available
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References
No Data Available
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