Substance

ID:324878

Tris(dibenzylideneacetone)dipalladium(0)

Names and Identifiers
IUPAC Traditional name
tris(dibenzylideneacetone) dipalladium
IUPAC name
tris(1,5-diphenylpenta-1,4-dien-3-one) dipalladium
Synonyms
Pd2(dba)3Tris(dibenzylideneacetone)dipalladium(0)三(二亚苄基丙酮)二钯(0)Pd2dba3
Registration numbers
CAS Number
MDL Number
PubChem SID
Properties
Product Information
Linear Formula
(C6H5CH=CHCOCH=CHC6H5)3Pd2
Purity
97%
Physical Property
Melting Point
152-155 °C(lit.)
Safety Information
German water hazard class
2
MSDS Link
Personal Protective Equipment
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Molecule Details
Packaging
1, 5, 25, 50, 100 g in glass bottle
500 mg in glass bottle
Application

• Catalyst for Suzuki coupling of aryl chlorides (eq. 1)
• Catalyst for Heck coupling of aryl chlorides (eq. 2)
• Catalyst for arylation of ketones (eq. 3)
• Catalyst for Buchwald-Hartwig amination of aryl halides (eq. 4)
• Catalyst for fluorination of allylic chlorides (eq. 5)
• Catalyst for β-arylation of carboxylic esters (eq. 6)
• Catalyst for carbonylation of 1,1-dichloro-1-alkenes (eq. 7)
• Catalyst for conversion of aryl and vinyl triflates to aryl and vinyl halides (eq. 8)
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsReactant involved in:
• Synthesis of nanosized palladium phosphides upon interaction with white phosphorous1
• Preparation of palladium triphenylphosphine carbonyl cluster complexes2
• Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions3
• Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes4Catalyst for:
• Suzuki cross-coupling reactions5
• PCN- and PCS-pincer palladium complex catalyzed tandem allylation6
Molecular Spectra
No Data Available
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References
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