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Substance
ID:324398
Structure
Similarity
Functional Group
Text
ID:32909
6-Methoxy-2-naphthaleneboronic acid
Sigma Aldrich
ID: 521892
Names and Identifiers
IUPAC name
(6-methoxynaphthalen-2-yl)boronic acid
IUPAC Traditional name
6-methoxynaphthalen-2-ylboronic acid
Synonyms
6-Methoxy-2-naphthylboronic acid
6-甲氧基-2-萘硼酸
6-Methoxy-2-naphthalenylboronic acid
6-Methoxy-2-naphthaleneboronic acid
6-Methoxynaphthalene-2-boronic acid
Registration numbers
CAS Number
156641-98-4
MDL Number
MFCD03093087
PubChem SID
24874233
Properties
Safety Information
Risk Statements
36/37/38
GHS Signal Word
Warning
European Hazard Symbols
Irritant (Xi)
GHS Hazard statements
H315
-
H319
-
H335
German water hazard class
3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
26
-
36
GHS Precautionary statements
P261
-
P305+P351+P338
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
MSDS Link
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Product Information
Linear Formula
C10H6OCH3B(OH)2
Purity
≥95%
Physical Property
Melting Point
>295 °C(lit.)
Molecule Details
General description
Contains varying amounts of anhydride.
Packaging
5 g in glass bottle
Application
Reactant for:
• Suzuki-Miyaura coupling1
• Enantioselective a-arylation of carbonyls via copper-bisoxazoline catalysis2
• Enantioselective synthesis of aryl ketones3
• Copper-catalyzed trifluoromethylation4
• Rhodium-catalyzed oxidative coupling with alkynes5
Molecular Spectra
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References
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