Substance
ID:319292
Names and Identifiers
Synonyms
Bis(2-methoxyethyl)aminosulfur trifluoride solution双(2-甲氧基乙基)氨基三氟化硫 溶液Deoxo-Fluor® 溶液Deoxo-Fluor® solution
IUPAC name
bis(2-methoxyethyl)(trifluoro-λ4-sulfanyl)amine
IUPAC Traditional name
bis(2-methoxyethyl)(trifluoro-λ4-sulfanyl)amine
Properties
Safety Information
European Hazard Symbols
Flammable (F)
Toxic (T)Storage Temperature
2-8°C
Supplemental Hazard Statements
Contact with water liberates toxic gas., Reacts violently with water.
UN Number
3286
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A,1B,2
Carcinogenicity, categories 1A,1B,2
Reproductive toxicity, categories 1A,1B,2
Specific Target Organ Toxicity – Single exposure, categories 1,2
Specific Target Organ Toxicity – Repeated exposure, categories 1,2
Aspiration Hazard, category 1
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
RID/ADR
UN 3286 3/PG 2
Packing Group
2
GHS Precautionary statements
P210-P231+P232-P261-P280-P301+P310-P422
Safety Statements
16-26-36/37/39-45-62
Personal Protective Equipment
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Risk Statements
63-11-14-23/25-29-35-48/20-65
Hazard Class
3
GHS Signal Word
Danger
MSDS Link
German water hazard class
3
GHS Hazard statements
H225-H261-H301+H331-H304-H314-H336-H361d-H373
Product Information
Concentration
~50% in toluene (NMR)
Empirical Formula (Hill Notation)
C6H14F3NO2S
Physical Property
Apperance
clear yellow liquid
Flash Point
<50 °F
<10 °C
Molecule Details
Other Notes
Fluorinating agent with high thermal stability 7,8,9,10
Application
Reactant for:
• Fluorination reactions1
• Preparation of fluorinated catechols via Umpolung based nucleophilic deoxyfluorination2
• Preparation of imidazole derivatives as CXCR3 antagonists3
• Ring expansion reactions4
• Synthesis of acyl azides from carboxylic acids5
• Aldehydes or ketones from carboxylic acids and Grignard reagents via in situ generation of Weinreb amides6
Legal Information
Deoxo-Fluor is a registered trademark of Air Products & Chemicals, Inc.
Fluorinating agent with high thermal stability 7,8,9,10
Application
Reactant for:
• Fluorination reactions1
• Preparation of fluorinated catechols via Umpolung based nucleophilic deoxyfluorination2
• Preparation of imidazole derivatives as CXCR3 antagonists3
• Ring expansion reactions4
• Synthesis of acyl azides from carboxylic acids5
• Aldehydes or ketones from carboxylic acids and Grignard reagents via in situ generation of Weinreb amides6
Legal Information
Deoxo-Fluor is a registered trademark of Air Products & Chemicals, Inc.
Molecular Spectra
No Data Available
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References
No Data Available
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