Substance
ID:317083
Names and Identifiers
IUPAC name
[(tert-butoxy)(dimethylamino)methyl]dimethylamine
Synonyms
Bredereck’s reagenttert-Butoxy bis(dimethylamino)methane叔丁氧基双(二甲胺基)甲烷Bredereck 试剂
IUPAC Traditional name
[tert-butoxy(dimethylamino)methyl]dimethylamine
Registration numbers
CAS Number
Beilstein Number
MDL Number
EC Number
PubChem SID
Properties
Product Information
Linear Formula
(CH3)3COCH[N(CH3)2]2
Safety Information
European Hazard Symbols
Irritant (Xi)RID/ADR
UN 1993 3/PG 3
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS Hazard statements
H226-H315-H319-H335
Packing Group
3
GHS Signal Word
Warning
MSDS Link
Hazard Class
3
Personal Protective Equipment
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
26
German water hazard class
3
Risk Statements
10-36/37/38
UN Number
1993
GHS Precautionary statements
P261-P305+P351+P338
Physical Property
Boiling Point
50-55 °C/15 mmHg(lit.)
Flash Point
41 °C
105.8 °F
Refractive Index
n20/D 1.422(lit.)
Density
0.844 g/mL at 25 °C(lit.)
Molecule Details
Application
Reagent for α-enamination of ketones and esters.5,6
Used for the enamination of active methylene and methyl groups.
Reactant for:
• Preparation of pyrroloquinazolines as photochemotherapeutic agents1
• Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition2
• Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction3
• Aminomethylenation reactions4
Packaging
1, 10 g in glass bottle
Reagent for α-enamination of ketones and esters.5,6
Used for the enamination of active methylene and methyl groups.
Reactant for:
• Preparation of pyrroloquinazolines as photochemotherapeutic agents1
• Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition2
• Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction3
• Aminomethylenation reactions4
Packaging
1, 10 g in glass bottle
Molecular Spectra
No Data Available
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References
No Data Available
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