Substance
ID:316327
Names and Identifiers
IUPAC Traditional name
tris(4-chlorophenyl)phosphane
IUPAC name
tris(4-chlorophenyl)phosphane
Synonyms
三(4-氯苯基)膦Tris(4-chlorophenyl)phosphineNSC 136459Tris(p-chlorophenyl)phosphine
Properties
Safety Information
Risk Statements
36/37/38
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements
P261-P305+P351+P338
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Safety Statements
26-37/39
GHS Hazard statements
H315-H319-H335
German water hazard class
3
MSDS Link
European Hazard Symbols
Irritant (Xi)GHS Signal Word
Warning
Physical Property
Melting Point
100-103 °C(lit.)
Product Information
Purity
95%
Linear Formula
(ClC6H4)3P
Molecule Details
Packaging
1 g in glass bottle
Application
Catalyst for:
• Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes1
• Solvent-free Heck reactions2Cocatalyst in:
• Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents3
• Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes4
• Rhodium-catalyzed hydrogenation reactions5
• Platinum-catalyzed allylation reactions6
1 g in glass bottle
Application
Catalyst for:
• Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes1
• Solvent-free Heck reactions2Cocatalyst in:
• Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents3
• Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes4
• Rhodium-catalyzed hydrogenation reactions5
• Platinum-catalyzed allylation reactions6
Molecular Spectra
No Data Available
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References
No Data Available
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