Substance

ID:316099

4-Formylphenylboronic acid

Names and Identifiers
IUPAC Traditional name
4-formylphenylboronic acid
IUPAC name
(4-formylphenyl)boronic acid
Synonyms
4-Boronobenzaldehydep-Formylphenylboronic acid4-(Dihydroxyboryl)benzaldehyde4-醛基苯硼酸对甲酰苯硼酸4-Formylbenzeneboronic acid4-Formylphenylboronic acid4-甲酰基苯硼酸p-Formylbenzeneboronic acid
Registration numbers
MDL Number
CAS Number
Beilstein Number
PubChem SID
Properties
Safety Information
GHS Pictograms
GHS05
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Safety Statements
22-26-36/37/39-45
Packing Group
3
Personal Protective Equipment
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Risk Statements
34
Hazard Class
8
GHS Hazard statements
H314-H317
MSDS Link
UN Number
1759
German water hazard class
3
European Hazard Symbols
Corrosive Corrosive (C)
GHS Precautionary statements
P280-P305+P351+P338-P310
RID/ADR
UN 1759 8/PG 3
GHS Signal Word
Danger
Product Information
Purity
≥95.0%
Linear Formula
HCOC6H4B(OH)2
Physical Property
Melting Point
237-242 °C(lit.)
Molecule Details
Other Notes
Contains varying amounts of anhydride
Packaging
1, 5, 25 g in glass bottle
Application
Reagent used for
• Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water1
• Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides2
• Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids3
• Triethylamine-catalyzed three-component Hantzsch condensations4
• Copper-catalyzed nitrations5
• Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta6
• Palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides7
• Palladium-catalyzed aerobic oxidative cross-coupling reactions8 Reagent used in Preparation of
• Sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells9
• A novel protein synthesis inhibitor active against Gram-positive bacteria10
Molecular Spectra
No Data Available
Click here to submit data
References
No Data Available
Click here to submit data