Substance
ID:309977
Names and Identifiers
IUPAC Traditional name
trimethylsilyl cyanide
IUPAC name
trimethylsilanecarbonitrile
Synonyms
Cyanotrimethylsilane三甲基氰硅烷TMSCNTrimethylsilyl cyanide氰化三甲基硅烷
Registration numbers
Beilstein Number
EC Number
CAS Number
MDL Number
PubChem SID
Properties
Product Information
Purity
98%
Linear Formula
(CH3)3SiCN
Physical Property
Flash Point
1 °C
33.8 °F
Boiling Point
114-117 °C(lit.)
Density
0.793 g/mL at 20 °C(lit.)
Refractive Index
n20/D 1.392(lit.)
Melting Point
8-11 °C(lit.)
Safety Information
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
GHS Hazard statements
H225-H300+H310+H330
European Hazard Symbols
Highly toxic (T+)
Flammable (F)GHS Signal Word
Danger
MSDS Link
GHS Precautionary statements
P210-P260-P264-P280-P284-P301+P310
RID/ADR
UN 3384 6.1/PG 1
Safety Statements
16-36/37/39-45
UN Number
3384
Packing Group
1
Supplemental Hazard Statements
Contact with water liberates toxic gas.
German water hazard class
3
Personal Protective Equipment
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Risk Statements
11-26/27/28-29
Hazard Class
6.1
Molecule Details
Application
Reacts with aldehydes and ketones to give cyanohydrin-TMS ethers which can be reduced to β-aminoethyl alcohols.
Reagent for the cyanosilylation of aldehydes in near quantitative yield via catalysis by silylene-bridged rare earth oxide complexes. Asymmetric cyanosilylation with chiral dinuclear Ti(IV) complexes.
Packaging
25 g in Sure/Seal™
5 g in glass bottle
Reacts with aldehydes and ketones to give cyanohydrin-TMS ethers which can be reduced to β-aminoethyl alcohols.
Reagent for the cyanosilylation of aldehydes in near quantitative yield via catalysis by silylene-bridged rare earth oxide complexes. Asymmetric cyanosilylation with chiral dinuclear Ti(IV) complexes.
Packaging
25 g in Sure/Seal™
5 g in glass bottle
Molecular Spectra
No Data Available
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References
No Data Available
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