Substance

ID:309832

Names and Identifiers
IUPAC name
tribromoborane
IUPAC Traditional name
boron tribromide
Synonyms
Boron tribromide三溴化硼Tribromoboron
Registration numbers
CAS Number
EC Number
MDL Number
PubChem SID
Properties
Physical Property
Flash Point
195.8 °F
91 °C
Density
2.60 g/mL at 20 °C(lit.)
Apperance
colorless
Vapor Pressure
40 mmHg ( 14 °C)
Boiling Point
~90 °C(lit.)
Vapor Density
8.6 (vs air)
Melting Point
-46 °C(lit.)
Safety Information
GHS Pictograms
GHS05
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS06
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Personal Protective Equipment
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
European Hazard Symbols
Highly toxic Highly toxic (T+)
Corrosive Corrosive (C)
Hazard Class
8
MSDS Link
RID/ADR
UN 2692 8/PG 1
GHS Hazard statements
H300-H314-H330
Risk Statements
14-26/28-35
GHS Signal Word
Danger
Safety Statements
9-26-28-36/37/39-45
Supplemental Hazard Statements
Reacts violently with water.
GHS Precautionary statements
P260-P264-P280-P284-P305+P351+P338-P310
German water hazard class
3
RTECS
ED7400000
UN Number
2692
Packing Group
1
Product Information
Grade
ReagentPlus®
Purity
99.9%
Empirical Formula (Hill Notation)
BBr3
Molecule Details
Application
Used to cleave aryl methyl ethers in a syntheses of a benzopyranobenzopyran from a coumarin scaffold11 and ladder-type conjugated polymers.12
Reactant for preparation of:
• Drug intermediate 6-nitro-L-DOPA1
• Luminescent polystyrene derivatives with sterically protected carbazolylborane moieties2
• High-quality boron-doped graphene via Wurtz-type reductive coupling reaction3
• Mercapto-(+)-methamphetamine haptens for synthesis of (+)-methamphetamine conjugate vaccines with improved epitope densities4
• Micrometer-sized organic molecule-DNA hybrid structures5
• Borane complexes via electrophilic aromatic borylation reactions6
• A 5-HT2C receptor agonist7
• Biphenyl-derivatives possessing tertiary amino groups as β-secretase(BACE1) inhibitors for the treatment of Alzheimer′s disease8
• A highly near-IR region fluorescent p-extended boron aza-dipyrromethene moiety unit9
• Tetrahydroisoquinoline derivatives via intramolecular cyclization of methoxy-substituted N-phenethylimides10
Packaging
100, 250 g in Sure/Seal™
2 kg in Sure/Seal™
25 g in ampule
Legal Information
ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC
Molecular Spectra
No Data Available
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References
No Data Available
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