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Substance
ID:309470
Structure
Similarity
Functional Group
Text
ID:88495
(R)-(-)-5,5-Dimethyl-4-phenyl-2-oxazolidinone
Sigma Aldrich
ID: 450707
Names and Identifiers
IUPAC name
(4R)-5,5-dimethyl-4-phenyl-1,3-oxazolidin-2-one
IUPAC Traditional name
(4R)-5,5-dimethyl-4-phenyl-1,3-oxazolidin-2-one
Synonyms
(R)-(-)-5,5-Dimethyl-4-phenyl-2-oxazolidinone
(R)-(-)-5,5-二甲基-4-苯-2-噁唑烷酮
Registration numbers
CAS Number
170918-42-0
MDL Number
MFCD00274261
PubChem SID
24868261
Properties
Product Information
Empirical Formula (Hill Notation)
C11H13NO2
Purity
98%
Optical Purity
ee: 99% (HPLC)
Safety Information
European Hazard Symbols
Irritant (Xi)
GHS Signal Word
Warning
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
GHS Hazard statements
H315
-
H319
-
H335
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Safety Statements
26
-
36
German water hazard class
3
MSDS Link
Download link
Risk Statements
36/37/38
GHS Precautionary statements
P261
-
P305+P351+P338
Physical Property
Optical Rotation
[α]25/D -71°, c = 2 in chloroform
Melting Point
151-156 °C(lit.)
Molecule Details
Application
Versatile chiral auxiliary for asymmetric synthesis used in diastereoselective Michael additions.1
Packaging
250 mg in glass bottle
Molecular Spectra
No Data Available
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References
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