Substance

ID:309281

Trimethylaluminum solution

Names and Identifiers
IUPAC name
trimethylalumane
IUPAC Traditional name
trimethylaluminium
Synonyms
三甲基铝 溶液Trimethylaluminum solution
Registration numbers
MDL Number
Beilstein Number
CAS Number
PubChem SID
Properties
Safety Information
GHS Pictograms
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS05
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS08
Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A,1B,2
Carcinogenicity, categories 1A,1B,2
Reproductive toxicity, categories 1A,1B,2
Specific Target Organ Toxicity – Single exposure, categories 1,2
Specific Target Organ Toxicity – Repeated exposure, categories 1,2
Aspiration Hazard, category 1
GHS09
Hazardous to the aquatic environment
Acute hazard, category1
Chronic hazard, categories 1,2
GHS02
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Packing Group
1
European Hazard Symbols
Flammable Flammable (F)
Corrosive Corrosive (C)
Nature polluting Nature polluting (N)
Safety Statements
16-26-36/37/39-45-61-62
German water hazard class
2
GHS Hazard statements
H225-H250-H260-H304-H314-H336-H361-H373-H411
MSDS Link
Hazard Class
4.2
UN Number
3394
RID/ADR
UN 3394 4.2/PG 1
Risk Statements
11-14-17-34-48/20-51/53-62-65-67
GHS Signal Word
Danger
GHS Precautionary statements
P210-P222-P223-P231+P232-P370+P378-P422
Supplemental Hazard Statements
Reacts violently with water.
Physical Property
Flash Point
-.4 °F
-18 °C
Density
0.683 g/mL at 25 °C
Product Information
Linear Formula
(CH3)3Al
Concentration
2.0 M in hexanes
Molecule Details
Packaging
100, 800 mL in Sure/Seal™
Application
Used with 4-bromo-2,6-di-tert-butylphenol (cat. no. 394378) to prepare a wide range of carbonyl compounds via the selective rearrangement of epoxides.1,2
Molecular Spectra
No Data Available
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References
No Data Available
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