Substance

ID:309089

(-)-DIP-Bromide™

Names and Identifiers
Synonyms
(1R)-(-)-B-Bromodiisopinocampheylborane(1R)-(-)-B-溴二异松蒎烯基硼烷(-)-DIP-Bromide™
IUPAC Traditional name
bromobis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]borane
IUPAC name
bromobis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]borane
Registration numbers
CAS Number
MDL Number
PubChem SID
Properties
Safety Information
GHS Precautionary statements
P280-P305+P351+P338-P310
German water hazard class
3
RID/ADR
UN 3261 8/PG 2
Safety Statements
26-27-28-36/37/39-45
MSDS Link
European Hazard Symbols
Corrosive Corrosive (C)
Risk Statements
34
GHS Hazard statements
H314
GHS Pictograms
GHS05
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Personal Protective Equipment
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Class
8
GHS Signal Word
Danger
Packing Group
2
UN Number
3261
Product Information
Empirical Formula (Hill Notation)
C20H34BBr
Purity
95%
Molecule Details
Application
Both enantiomers have been used for asymmetric reduction of prochiral ketones, enolboration reactions, and opening of meso-epoxides to form non-racemic halohydrins.1
Packaging
25 g in glass bottle
Legal Information
DIP-Bromide is a trademark of Sigma-Aldrich Co. LLC
Molecular Spectra
No Data Available
Click here to submit data
References
No Data Available
Click here to submit data