Substance
ID:308986
Names and Identifiers
IUPAC name
2,2,6,6-tetramethyl-N,N,3,5-tetrakis(trimethylsilyl)-3,5-diaza-2,6-disila-4-ceraheptan-4-amine
Synonyms
Tris[N,N-bis(trimethylsilyl)amide]cerium(III)三[N,N-双(三甲基硅基)酰胺]铈(III)1,1,1-Trimethyl-N-(trimethylsilyl)silanamine cerium(III) salt
IUPAC Traditional name
2,2,6,6-tetramethyl-N,N,3,5-tetrakis(trimethylsilyl)-3,5-diaza-2,6-disila-4-ceraheptan-4-amine
Properties
Physical Property
Flash Point
2 °C
35.6 °F
Apperance
solid
Melting Point
132-140 °C(lit.)
Product Information
Linear Formula
Ce(N(Si(CH3)3)2)3
Purity
96%
Safety Information
Risk Statements
11-14/15-34
Safety Statements
7/8-16-26-36/37/39-43-45
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Supplemental Hazard Statements
Reacts violently with water.
Personal Protective Equipment
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
German water hazard class
3
RID/ADR
UN 3396 4.3/PG 2
Hazard Class
4.3
Packing Group
2
GHS Signal Word
Danger
GHS Precautionary statements
P210-P231+P232-P280-P305+P351+P338-P310-P422
European Hazard Symbols
Corrosive (C)
Flammable (F)MSDS Link
GHS Hazard statements
H228-H261-H314
UN Number
3396
Molecule Details
Packaging
1 g in glass bottle
Application
Reactant for synthesis of:
• Amidocerium(IV) oxides1
• Sterically encumbered N-heterocyclic carbene ligands2
• Lanthanide imidodiphosphinate complexes with electroluminescent properties3
• Lanthanide complexes of an oxazoline-phenoxide hybrid chelate4Reactant for:
• One-electron oxidation to produce tetravalent cerium compounds5
• Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes6
1 g in glass bottle
Application
Reactant for synthesis of:
• Amidocerium(IV) oxides1
• Sterically encumbered N-heterocyclic carbene ligands2
• Lanthanide imidodiphosphinate complexes with electroluminescent properties3
• Lanthanide complexes of an oxazoline-phenoxide hybrid chelate4Reactant for:
• One-electron oxidation to produce tetravalent cerium compounds5
• Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes6
Molecular Spectra
No Data Available
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References
No Data Available
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