Substance
ID:307491
Names and Identifiers
Synonyms
Tricyclopentylphosphine三环戊基膦
IUPAC name
tricyclopentylphosphane
IUPAC Traditional name
tricyclopentylphosphane
Registration numbers
CAS Number
MDL Number
Beilstein Number
EC Number
PubChem SID
Properties
Product Information
Empirical Formula (Hill Notation)
C15H27P
Purity
97%
Safety Information
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Hazard Class
4.2
GHS Precautionary statements
P222-P231-P280-P305+P351+P338-P310-P422
Risk Statements
17-34
Personal Protective Equipment
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
26-36/37/39-45
European Hazard Symbols
Corrosive (C)
Flammable (F)UN Number
2845
GHS Hazard statements
H250-H314
Packing Group
1
German water hazard class
3
GHS Signal Word
Danger
MSDS Link
RID/ADR
UN 2845 4.2/PG 1
Physical Property
Refractive Index
n20/D 1.538(lit.)
Density
0.986 g/mL at 20 °C(lit.)
0.979 g/mL at 25 °C
Flash Point
410 °F
210 °C
Molecule Details
Packaging
1, 5 g in glass bottle
Application
Cocatalyst for:
• Nickel-catalyzed cycloaddition of enones and alkynes1
• Rhodium-catalyzed allylation of aldehydes with homoallylic alcohols2
• Hydrocarbamoylation of alkynes by nickel/Lewis-acid catalysis3
• Alkenylation of imidazoles by nickel/Lewis acid catalysis
• Palladium-catalyzed Negishi cross-coupling reactions4
• PHosphine-catalyzed synthesis of 6-substituted 2-pyrones5
1, 5 g in glass bottle
Application
Cocatalyst for:
• Nickel-catalyzed cycloaddition of enones and alkynes1
• Rhodium-catalyzed allylation of aldehydes with homoallylic alcohols2
• Hydrocarbamoylation of alkynes by nickel/Lewis-acid catalysis3
• Alkenylation of imidazoles by nickel/Lewis acid catalysis
• Palladium-catalyzed Negishi cross-coupling reactions4
• PHosphine-catalyzed synthesis of 6-substituted 2-pyrones5
Molecular Spectra
No Data Available
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References
No Data Available
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