Substance
ID:306549
Names and Identifiers
IUPAC name
13-(2-{13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-yl}phenyl)-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2,4,6,8,10,16,18,20,22-decaene
Synonyms
(R,R)-1,2-Bis[(R)-4,5-dihydro-3H-binaphtho(1,2-c:2′,1′-e)phosphepino]benzene(R)-BINAPHANE(R,R)-1,2-二[(R)-4,5-二氢-3H-联萘并(1,2-c:2′,1′-e)磷杂庚英并]苯(R)-联萘
IUPAC Traditional name
13-(2-{13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-yl}phenyl)-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2,4,6,8,10,16,18,20,22-decaene
Properties
Safety Information
MSDS Link
German water hazard class
3
Personal Protective Equipment
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Physical Property
Melting Point
>200 °C (dec.)
Product Information
Empirical Formula (Hill Notation)
C50H36P2
Molecule Details
Application
(R)-Binaphane shows excellent enantioselectivity (up to >99% ee) for hydrogenation of E/Z-isomeric mixtures of β-substituted arylenamides.6
Chiral Quest Phosphine Ligands for Asymmetric HydrogenationCatalyst involved in:
• Enantioselective anilinosulfonamide allyl alcohol cyclization1
• Synthesis of β-trifluoromethyl α-amino acids2
• Phosphine-catalyzed cycloadditions of aldehydes and ketoketenes3
• Dimerization of ketoketenes4
• Enantioselective carbonyl-ene reactions via palladium and platinum derivatives5
(R)-Binaphane shows excellent enantioselectivity (up to >99% ee) for hydrogenation of E/Z-isomeric mixtures of β-substituted arylenamides.6
Chiral Quest Phosphine Ligands for Asymmetric HydrogenationCatalyst involved in:
• Enantioselective anilinosulfonamide allyl alcohol cyclization1
• Synthesis of β-trifluoromethyl α-amino acids2
• Phosphine-catalyzed cycloadditions of aldehydes and ketoketenes3
• Dimerization of ketoketenes4
• Enantioselective carbonyl-ene reactions via palladium and platinum derivatives5
Molecular Spectra
No Data Available
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References
No Data Available
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