Substance
ID:305974
Chlorocyclopentadienyl[(4S,5S)-2,2-dimethyl-α,α,α′,α′-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium
Names and Identifiers
Synonyms
[(4S,5S)-2,2-Dimethyl-1,3-dioxolan-4,5-bis(diphenylmethoxy)]cyclopentadienyl-chlorotitaniumChlorocyclopentadienyl[(4S,5S)-2,2-dimethyl-α,α,α′,α′-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium[(4S,5S)-2,2-二甲基-1,3-二氧戊环-4,5-双(二苯基甲氧基)]环戊二烯基-氯化钛(S,S)-Duthaler-Hafner reagent(4S,5S)-Chloro-cyclopentadienyl-[2,2-dimethyl-1,3-dioxolan-4,5-bis(diphenylmethoxy)]titanium(4S,5S)-氯-环戊二烯基-[2,2-二甲基,-1,3-二氧戊环-4,5-双(二苯基甲氧基)]钛氯环戊二烯基[(4S,5S)-2,2-二甲基-α,α,α′,α′-四苯基-1,3-二氧戊环-4,5-二甲醇酸根]钛
IUPAC name
[(4S,5S)-5-(hydroxydiphenylmethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]diphenylmethanol; chlorotitaniumylium; cyclopenta-2,4-dien-1-ide
IUPAC Traditional name
[(4S,5S)-5-(hydroxydiphenylmethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]diphenylmethanol; chlorotitaniumylium; cyclopentadienide
Properties
Safety Information
UN Number
3261
Personal Protective Equipment
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
MSDS Link
Safety Statements
26-36/37/39-45
GHS Signal Word
Danger
Risk Statements
34
Hazard Class
8
GHS Hazard statements
H314
European Hazard Symbols
Corrosive (C)German water hazard class
3
Packing Group
2
GHS Precautionary statements
P280-P305+P351+P338-P310
RID/ADR
UN 3261 8/PG 2
Product Information
Purity
97%
Empirical Formula (Hill Notation)
C36H33ClO4Ti
Physical Property
Melting Point
209-213 °C(lit.)
Optical Rotation
[α]20/D +246°, c = 1 in chloroform
Molecule Details
Packaging
100, 500 mg in glass bottle
Application
ApplicationA novel highly enantioselective allyl-transfer reagent. Excellent regio-, diastereo-, and enantioselectivities (usually >95% ee, >95% de) are obtained for the addition of allyl nucleophiles to aldehydes.1ium trichloride can be easily recovered.5117application
100, 500 mg in glass bottle
Application
ApplicationA novel highly enantioselective allyl-transfer reagent. Excellent regio-, diastereo-, and enantioselectivities (usually >95% ee, >95% de) are obtained for the addition of allyl nucleophiles to aldehydes.1ium trichloride can be easily recovered.5117application
Molecular Spectra
No Data Available
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References
No Data Available
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